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Elsevier, Tetrahedron Letters, 33(53), p. 4409-4412

DOI: 10.1016/j.tetlet.2012.06.041

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Ruthenium(II) pincer complexes with oxazoline arms for efficient transfer hydrogenation reactions

Journal article published in 2012 by Tao Chen, Lipeng He, Dirong Gong, Limin Yang, Xiaohe Miao, Jorg Eppinger, Kuo-Wei Huang ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Well-defined P NN CN pincer ruthenium complexes bearing both strong phosphine and weak oxazoline donors were developed. These easily accessible complexes exhibit significantly better catalytic activity in transfer hydrogenation of ketones compared to their PN 3P analogs. These reactions proceed under mild and base-free conditions via protonation- deprotonation of the 'NH' group in the aromatization-dearomatization process. © 2012 Elsevier Ltd. All rights reserved.