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Elsevier, Tetrahedron, 31(68), p. 6152-6157, 2012
DOI: 10.1016/j.tet.2012.05.075
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Homocoupling of benzyl halides catalyzed by POCOP-nickel pincer complexes
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Abstract
Two types of POCOP-nickel(II) pincer complexes were prepared by mixing POCOP pincer ligands and NiX 2 in toluene at reflux. The resulting nickel complexes efficiently catalyze the homocoupling reactions of benzyl halides in the presence of zinc. The coupled products were obtained in excellent to quantitative yields. © 2012 Elsevier Ltd. All rights reserved.