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Elsevier, Journal of Molecular Spectroscopy, 1-2(267), p. 19-22

DOI: 10.1016/j.jms.2011.01.008

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The WEAKLY--BOUND CO$_2$--ACETYLENE COMPLEX: FUNDAMENTAL AND TORSIONAL COMBINATION BAND IN THE CO$_2$ $ν_3$ REGION

Journal article published in 2011 by Clément Lauzin ORCID, J. Norooz Oliaee, M. Rezaei, N. Moazzen-Ahmadi
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Infrared spectrum of the weakly-bound CO$_2$--C$_2$H$_2$ complex in the region of the CO$_2$ $ν_3$ fundamental band ($∼$ 2349 cm$^{-1}$) is observed in a pulsed supersonic slit jet expansion using a tunable diode laser probe. Two bands are observed and analyzed: the fundamental (C--O asymmetric stretch) and a combination involving the intermolecular torsional (out-of-plane bend) vibration. The resulting torsional frequency is 44.385(10) cm$^{-1}$. This represents the first observation of an intermolecular frequency for carbon dioxide-acetylene complex. A comparison between the results obtained here and those previously reported for N$_2$O--C$_2$H$_2$ complex is discussed. ; Author Institution: Laboratoire de Chimie quantique et Photophysique, CP160/09 Faculte des Sciences, Universite Libre de Bruxelles (U.L.B.), Ave. Roosevelt, 50 B-1050 Brussels, Belgium; Department of Physics and Astronomy, University of Calgary, Calgary, AB T2N; 1N4, Canada