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A new functionalizable polyoxometalate platform: The heptanuclear Co(II) polyoxometalate complex [{(B-α- PW(9) O(34) )Co(3) (OH)(H(2) O)(2) (O(3) PC(O)- (C(3) H(6) NH(3) )PO(3) )}(2) Co](14-) represents a unique example of a magnetic, stable, functionalizable polyoxotungstate platform, and behaves as a single-molecule magnet.