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Wiley, Angewandte Chemie International Edition, 50(55), p. 15539-15543

DOI: 10.1002/anie.201608081

Wiley, Angewandte Chemie, 50(128), p. 15768-15772

DOI: 10.1002/ange.201608081

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Experimental and computational studies of the copper borate complexes [(NHC)Cu(HBEt3)] and [(NHC)Cu(HB(C6F5)3)]

Journal article published in 2016 by Lee R. Collins, Nasir A. Rajabi, Stuart A. MacGregor ORCID, Mary F. Mahon, Michael K. Whittlesey ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

The synthesis of the Cu-borate complexes [(6Mes)Cu(HBR3)] featuring the unusual [HBEt3]− (5) and [HB(C6F5)3]− (6) ligands is described. Experimental and computational studies show both compounds feature a direct Cu–H interaction, but that while 5 is two-coordinate, 6 displays an additional, stabilizing Cu–Cipso(C6F5) interaction.