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Taylor and Francis Group, Phosphorus, Sulfur, and Silicon and the Related Elements, 2(192), p. 241-244, 2016

DOI: 10.1080/10426507.2016.1255623

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Role of electron transfer processes in the oxidation of aryl sulfides catalyzed by nonheme iron complexes

Journal article published in 2016 by Alessia Barbieri, Stefano Di Stefano, Osvaldo Lanzalunga, Andrea Lapi, Marco Mazzonna, Giorgio Olivo ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The oxidation of a series of aryl 1-methyl-1-phenylethyl sulfides with H2O2 catalyzed by two tetradentate nonheme-iron complexes [(PDP)FeII(SbF6)2] and [(BPMCN)FeII(OTf)2] occurs by an electron transfer-oxygen transfer (ET/OT) mechanism as supported by the observation of products deriving from fragmentation of the corresponding radical cations in association with S-oxidation products (sulfoxides)