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American Chemical Society, Chemistry of Materials, 19(28), p. 7066-7071, 2016

DOI: 10.1021/acs.chemmater.6b02943

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Thin Films of (Fe1–xCox)3P and Fe3(P1–xTex) from the Co-Decomposition of Organometallic Precursors by MOCVD

Journal article published in 2016 by Andrew P. Leitner, Jing-Han Chen, Desmond E. Schipper ORCID, Kenton H. Whitmire ORCID
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

A new method for preparing thin films of ternary transition metal phosphides has been developed. The ferromagnetic compound Fe3P has been doped with cobalt and tellurium by decomposing H2Fe3(CO)9PtBu with either Co3(CO)9PtBu or H2Fe3(CO)9Te via metal–organic chemical vapor deposition (MOCVD) onto a quartz substrate. Solid mixtures of the organometallic clusters were vaporized and decomposed at 400 °C to produce films that were subsequently annealed under vacuum at 650 °C for 24 h to afford crystalline films of (Fe1–xCox)3P (0.09