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American Physical Society, Physical review B, 18(95)

DOI: 10.1103/physrevb.95.184516

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Is BaCr$_2$As$_2$ symmetrical to BaFe$_2$As$_2$ with respect to half $3d$ shell filling?

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

We have performed an angle-resolved photoemission spectroscopy study of BaCr$_2$As$_2$, which has the same crystal structure as BaFe$_2$As$_2$, a parent compound of Fe-based superconductors. We determine the Fermi surface of this material and its band dispersion over 5 eV of binding energy. Very moderate band renormalization (1.35) is observed for only two bands. We attribute this small renormalization to enhanced direct exchange as compared to Fe in BaFe$_2$As$_2$, and to a larger contribution of the $e_g$ orbitals in the composition of the bands forming the Fermi surface, leading to an effective valence count that is reduced by Fe $d$ - As $p$ hybridization. ; Comment: 6 pages, 4 figures