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Wiley, Advanced Synthesis & Catalysis, 23(358), p. 3765-3769, 2016

DOI: 10.1002/adsc.201601106

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Synthesis of functionalized hydrazines: facile homogeneous (n-heterocyclic carbene)-palladium(0)-catalyzed diboration and silaboration of azobenzenes

Journal article published in 2016 by Melvyn B. Ansell, George E. Kostakis ORCID, Holger Braunschweig, Oscar Navarro Fernandez, John Spencer
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The bis(N-heterocyclic carbene)(diphenylacetylene)palladium complex [Pd(ITMe)2(PhC≡CPh)] (ITMe=1,3,4,5 tetramethylimidazol-2-ylidene) acts as a highly active pre catalyst in the diboration and silaboration of azobenzenes to synthesize a series of novel functionalized hydrazines. The reactions proceed using commercially available diboranes and silaboranes under mild reaction conditions.