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Wiley, Advanced Synthesis & Catalysis, 23(358), p. 3765-3769, 2016
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Synthesis of functionalized hydrazines: facile homogeneous (n-heterocyclic carbene)-palladium(0)-catalyzed diboration and silaboration of azobenzenes
Journal article published in 2016 by
Melvyn B. Ansell,
George E. Kostakis 
,
Holger Braunschweig,
Oscar Navarro Fernandez,
John Spencer
,
Holger Braunschweig,
Oscar Navarro Fernandez,
John Spencer
This paper is made freely available by the publisher.
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Abstract
The bis(N-heterocyclic carbene)(diphenylacetylene)palladium complex [Pd(ITMe)2(PhC≡CPh)] (ITMe=1,3,4,5 tetramethylimidazol-2-ylidene) acts as a highly active pre catalyst in the diboration and silaboration of azobenzenes to synthesize a series of novel functionalized hydrazines. The reactions proceed using commercially available diboranes and silaboranes under mild reaction conditions.