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American Chemical Society, Journal of Organic Chemistry, 19(78), p. 9914-9920, 2013

DOI: 10.1021/jo401674v

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Chemically Triggered C-ON Bond Homolysis of Alkoxyamines. 8. Quaternization and Steric Effects

Journal article published in 2013 by Gérard Audran, Lionel Bosco, Paul Brémond, Sylvain R. A. Marque ORCID, Valérie Roubaud, Didier Siri ORCID
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

WOS:000326320100037 ; International audience ; The C-ON bond homolysis in alkoxyamine 2a was chemically triggered by quaternization of the 1-(pyridin-2-yl)ethyl fragment using protonation, acylation, and oxidation into the N-oxide. The solvent effect was also investigated, and DFT calculations were performed to explore this chemical activation. Alkoxyamines 2a-d were also compared to the 1-(pyridin-4-yl)ethyl analogues 3a-d.