Published in

American Institute of Physics, Journal of Applied Physics, 17(119), p. 175104

DOI: 10.1063/1.4948337

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Crystalline-amorphous silicon nano-composites: Nano-pores and nano-inclusions impact on the thermal conductivity

Journal article published in 2016 by Maxime Verdier, Konstantinos Termentzidis ORCID, David Lacroix
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The thermal conductivities of nanoporous and nanocompositesilicon with incorporated amorphous phases have been computed by molecular dynamics simulations. A systematic investigation of the porosity and the width of the amorphous shell contouring a spherical pore has been made. The impact of amorphous phase nanoinclusions in a crystalline matrix has also been studied with the same amorphous fraction as the porosity of nanoporoussilicon to achieve comparison. The key parameter for all configurations with or without the amorphous phase is proved to be the interface (between the crystalline and amorphous phases or crystalline and void) to volume ratio. We obtain the sub-amorphous thermal conductivity for several configurations by combining pores, amorphous shell, and crystalline phase. These configurations are promising candidates for low cost and not toxic thermoelectric devices based on abundant semiconductors.