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International Union of Crystallography, Acta Crystallographica Section E: Crystallographic Communications, 12(72), p. 1848-1851, 2016

DOI: 10.1107/s2056989016018508

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Crystal structure of bis(bis{μ3-3-methyl-3-[(4-nitro-2-oxidobenzylidene)amino]propane-1,3-diolato}tris[chlorido(dimethyl sulfoxide)iron(III)]) dimethyl sulfoxide heptasolvate dihydrate

Journal article published in 2016 by Eduard Chygorin, Yuri Smal, Irina V. Omelchenko ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The title compound, [Fe3(C11H11N2O5)2Cl3(C2H6OS)3]2·7C2H6OS·2H2O, was isolated accidentally from an Fe0–NiCl2·6H2O–H3L–TEA–DMSO system [where H3Lis the product of the condensation betweenp-nitrosalicylaldehyde and 2-amino-2-methylpropane-1,3-diol and dimethyl sulfoxide (DMSO), and TEA is triethylamine]. The structure is based on a trinuclear {Fe3(μ-O)4} core, with an angular arrangement of the FeIIIions that can be explained by the geometrical restrictions of two bulky ligands, each coordinating to all of the metal cations.