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Isoxazoline-fused chlorins were obtained in moderate yields from the reaction of silyl nitronates and 5,10,15,20-tetra(pentafluorophenyl)porphyrin in toluene at 85 °C. ; PUBLISHED ; This work was supported by a grant from Science Foundation of Ireland (SFI 09/IN.1/B2650). MME thanks IRCSET for a postdoctoral fellowship.