Published in

European Geosciences Union, Atmospheric Chemistry and Physics Discussions, p. 1-32

DOI: 10.5194/acp-2016-494

Links

Tools

Export citation

Search in Google Scholar

Direct observations of organic aerosols in common wintertime hazes in North China: insights into their size, shape, mixing state, and source

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

Full text: Download

Green circle
Preprint: archiving allowed
Green circle
Postprint: archiving allowed
Green circle
Published version: archiving allowed
Data provided by SHERPA/RoMEO

Abstract

Many studies have focused on the physicochemical properties of aerosol particles in unusually severe haze episodes instead of the more freqent and less severe hazes. Consistent with this lack of attention, the morphology and mixing state of organic matter (OM) particles in the frequent light and moderate (L&M) hazes in winter in North China Plain (NCP) have not been examined, even though OM dominates these fine particles. In the present work, morphology, mixing state, and size of organic aerosols in the L&M hazes were systematically characterized using transmission electron microscopy coupled with energy-dispersive X-ray spectroscopy, atomic force microscopy, and nanoscale secondary ion mass spectrometer, with the comparisons among an urban site (Jinan, S1), a mountain site (Tai, S2), and a background island site (Changdao, S3) in the same hazes. Based on their morphology, the OM particles were divided into six different types: spherical (type 1), near-spherical (type 2), irregular (type 3), domelike (type 4), dispersed-OM (type 5), and OM-coating (type 6). In the three sampling sites, type 1–3 of OM particles were most abundant in the L&M hazes and most of them were internally mixed with non-OM particles. The abundant near-spherical OM particles with higher sphericity and lower aspect ratio indicate that these primary OM particles formed in cooling, polluted plumes from coal combustion and biomass burning. Based on the Si-O-C ratio in OM particles, we estimated that 71 % of type 1–3 OM particles were associated with coal combustion. Our result suggests that coal combustion in residential stoves was a widespread source from urban to rural areas in the NCP. Average OM thickness which correlates with the age of the air masses in type 6 particles only slightly increased from S3 to S2 to S1, suggesting that the L&M hazes were usually dry (relative humidity