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Synthesis, structure and reactivity of stable homoleptic gold(i) alkene cations.

Journal article published in 2009 by Tn Hooper, Cp Butts, Michael Green, Mairi.���F Haddow ORCID, Je McGrady ORCID, Ca Russell ORCID
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

Stable gold(I) cations: Treatment of [AuCI(SMe 2)] with AgSbF 6 in CH 2CI 2 at room temperature in the presence of norbornene leads smoothly to the formation of a complex containing the homoleptic tris (eta; 2-norbornene)gold(I) cation (see figure). The complex shows appreciable stability in the solid state and may be stabilised in solution by the addition of excess norbornene. © 2009 Wiley-VCH Verlag GmbH and Co. KGaA.