Links

Tools

Export citation

Search in Google Scholar

Facile, metal promoted, oxidation of η4-1,3-diphosphacyclobutadiene by water or methanol: synthesis of [MoCl(CO)(η4-1,3-P2C2But2)(η5-L)] (L = C5H5, C5Me5) and [MoCl(CO){η3,λ3,λ5-PC2But2PH(OR)}(η5-L)] (L= C5H5,R = H, Me)

Journal article published in 1999 by Andrew S. Weller, Christopher D. Andrews, Andrew D. Burrows ORCID, Michael Green, Jason M. Lynam, Mary F. Mahon, Cameron Jones
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

Full text: Unavailable

Question mark in circle
Preprint: policy unknown
Upload
Question mark in circle
Postprint: policy unknown
Upload
Question mark in circle
Published version: policy unknown
Upload

Abstract

The new complexes [MoCl(CO)(η4-1,3-P2C2Bu(t)2)(η5-L)] (L = C5H5 1, C5Me5 2) are reported; facile oxidation of 1 with water or methanol affords a rare example of a mixed valence phosphaphosphonietinyl in [MoCl(CO){η3,λ3,λ5-PC2Bu(t)2-PH(OR)}(η5-C5H5)] (R = H, Me), which has also been structurally characterised for R = H.