Published in

International Union of Crystallography, Journal of Applied Crystallography, 2(49), p. 556-560, 2016

DOI: 10.1107/s1600576716002405

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Origin of forbidden reflections in multiferroic Ba<sub>2</sub>CoGe<sub>2</sub>O<sub>7</sub>by neutron diffraction: symmetry lowering or Renninger effect?

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

For a symmetry-consistent theoretical description of the multiferroic phase of Ba2CoGe2O7a precise knowledge of its crystal structure is a prerequisite. In a previous synchrotron X-ray diffraction experiment on multiferroic Ba2CoGe2O7at room temperature, forbidden reflections were found that favour the tetragonal-to-orthorhombic symmetry lowering of the compound [Hutanu, Sazonov, Murakawa, Tokura, Náfrádi & Chernyshov (2011),Phys. Rev. B,84, 212101]. Here, the results are reported of room-temperature single-crystal diffraction studies with both hot and cold neutrons to differentiate between genuine symmetry lowering and multiple diffraction (the Renninger effect). A comparison of the experimental multiple diffraction patterns with simulated ones rules out symmetry lowering. Thus, the structural model based on the tetragonal space group P\overline{4}2_{1}m was selected to describe the Ba2CoGe2O7symmetry at room temperature. The precise structural parameters from neutron diffraction at 300 K are presented and compared with the previous X-ray diffraction results.