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American Chemical Society, Macromolecules, 6(49), p. 2054-2062, 2016

DOI: 10.1021/acs.macromol.5b02533

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Clickable Polylactic Acids by Fast Organocatalytic Ring-Opening Polymerization in Continuous Flow

Journal article published in 2016 by Sebastiaan A. Van Den Berg, Han Zuilhof, Tom Wennekes ORCID
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

The use of microreactor technology for the ring-opening polymerization of l-lactide catalyzed by 1,5,7-triazabicyclo[4.4.0]dec-5-ene allows for rapid optimization of reaction parameters (reaction temperature and residence time). At moderate catalyst loading, good control over the polymerization is demonstrated by high conversion of monomer (>95%) and low polydispersity (