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World Scientific Publishing, Journal of Porphyrins and Phthalocyanines, 02(14), p. 142-149, 2010

DOI: 10.1142/s1088424610001854

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Photoelectrochemical characterization of electrodepositedZnOthin films sensitized by octacarboxymetallophthalocyanine derivatives

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Hybrid thin films of crystalline zinc oxide ( ZnO ) modified by different octacarboxymetallophthalocyanines (MOCPc) were prepared by the readsorption method. Homogeneously blue or green thin films were formed. The photoelectrochemical characteristics of the electrodes were studied by time-resolved photocurrent measurements. Zinc(II) 2,3,9,10,16,17,23,24-octacarboxyphthalocyanine ( ZnOCPc ) showed considerably large quantum efficiency in sensitization of ZnO , one of the highest quantum efficiencies obtained so far with phthalocyanine-type sensitizers on nanocrystalline ZnO films.