World Scientific Publishing, Journal of Porphyrins and Phthalocyanines, 02(10), p. 69-75, 2006
DOI: 10.1142/s1088424606000090
Full text: Unavailable
The electrochemical and spectroscopic behavior of tantalum(V) phthalocyanine are presented. The NMR spectra is consistent with the lack of symmetry of the complex. Cyclic (CV) and square wave (SWV) voltammetries, and spectroelectrochemistry, were employed in the study of the complex. Two one-electron reductions and a simultaneous 4-electron reduction were observed. Reduction occurs first at the metal to form a Ta (IV) species, followed by ring based processes.