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EDP Sciences, EPJ Web of Conferences, (41), p. 05004, 2013

DOI: 10.1051/epjconf/20134105004

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Femtosecond Mid-Infrared Study of the Aqueous Solution Photochemistry of a CO-Releasing Molecule (CORM)

Journal article published in 2013 by P. Rudolf, F. Kanal, D. Gehrig, J. Niesel, T. Brixner ORCID, U. Schatzschneider, P. Nuernberger
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Ultraviolet irradiation of CO-releasing molecules (CORMs) in water eventually leads to the loss of several carbon monoxide ligands.We show for an exemplary manganese tricarbonyl CORM that only one ligand is photolyzed off on an ultrafast timescale and that some molecules may undergo geminate recombination.