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American Chemical Society, Energy and Fuels, 3(27), p. 1576-1585, 2013

DOI: 10.1021/ef4001456

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Experimental Study of Tetralin Oxidation and Kinetic Modeling of Its Pyrolysis and Oxidation

This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

Tetralin is the simplest polycyclic naphtheno-aromatic hydrocarbon found in liquid fuels (e.g., jet fuels, diesel). It is also produced by the pyrolysis and oxidation of decalin. To get a better understanding of tetralin combustion characteristics, new oxidation experiments were performed in a jet-stirred reactor, and the results are reported here. For the first time, stable species concentration profiles were measured at 1 and 10 atm over a range of equivalence ratios (φ = 0.5−1.5) and temperatures (790−1400 K). The oxidation of tetralin under these conditions was simulated using a semidetailed kinetic reaction scheme (∼10 000 reactions and ∼400 species) deriving from a chemical kinetic model proposed earlier for the oxidation of decalin over a wide range of conditions (jet-stirred reactor, plug-flow reactor, and shock-tube). The proposed kinetic model shows reasonable agreement with the present measurements. It can also be used to represent tetralin pyrolysis based on a variety of results available in the literature. Sensitivity analyses and reaction pathway computations were used for rationalizing the results.