AbstractThis paper gives out two kinds of novel well-behaved stimulated Brillouin scattering (SBS) mediums, FC-3283 and FC-770. Numerical calculation and experimental measurements show these two mediums both having lower absorption, higher optical loads and short phonon lifetime, which making them good candidate mediums for high-energy high-power SBS. Using them as the mediums in the compacted two-cell SBS phase-conjugation mirror, it is easily to generate ultrashort phased-conjugated Stokes pulses just with hundreds picoseconds. When the incident light energy is beyond 200 mJ, the pulse width of 8 ns can be compressed to 200 ps or less in both mediums. Especially, the FC-770 is very suitable to be chosen for generating the SBS picosecond pulses with the narrowest compression pulse width of 109 ps and the highest energy reflectivity of 80%.