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American Chemical Society, ACS Catalysis, 10(1), p. 1327-1330, 2011

DOI: 10.1021/cs200373f

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Differences in Catalytic Sites for CO Oxidation and Propylene Epoxidation on Au Nanoparticles

Journal article published in 2011 by Wen-Sheng Lee, Rong Zhang, M. Cem Akatay, Chelsey D. Baertsch, Eric A. Stach, Fabio H. Ribeiro ORCID, W. Nicholas Delgass
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

Sintering and increased Au loading of Au/TS-1 causes the rate of CO oxidation per mole of Au to increase, whereas that for epoxidation of propylene in O(2) and H(2) decreases. This opposite trend in rate behavior shows that the catalytic sites for the two reactions must be different.