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Wiley, Angewandte Chemie International Edition, 9(50), p. 2141-2143, 2011

DOI: 10.1002/anie.201005044

Wiley, Angewandte Chemie, 9(123), p. 2189-2191, 2011

DOI: 10.1002/ange.201005044

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Allylmalonate as an Activator Subunit for the Initiation of Relay Ring-Closing Metathesis Reactions

Journal article published in 2011 by Thomas R. Hoye, Junha Jeon ORCID, Manomi A. Tennakoon
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This paper is available in a repository.

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Abstract

Passing the baton: The relay ring-closing metathesis (RRCM) reaction of complex polyenes 1 has been studied. Several relay subunits (T) were examined and many did not sufficiently activate the RRCM. An allylmalonate-containing relay subunit solved this problem, and efficiently lead to the diene 2. TIPS=triisopropylsilyl.