Published in

Beilstein-Institut, Beilstein Journal of Organic Chemistry, (9), p. 2410-2416, 2013

DOI: 10.3762/bjoc.9.278

Links

Tools

Export citation

Search in Google Scholar

Synthesis of enantiopure sugar-decorated six-armed triptycene derivatives

Journal article published in 2013 by Paola Bonaccorsi, Maria Luisa Di Gioia, Antonella Leggio, Lucio Minuti, Teresa Papalia, Carlo Siciliano ORCID, Andrea Temperini, Anna Barattucci
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

Full text: Download

Orange circle
Preprint: archiving restricted
Upload
Orange circle
Postprint: archiving restricted
Upload
Green circle
Published version: archiving allowed
Upload
Policy details
Data provided by SHERPA/RoMEO

Abstract

A new class of molecules with a triptycene rigid core surrounded by six monosaccharide residues was synthesized. Hexakis(bromomethyl) substituted triptycene was converted into a six-armed triptycene azide (2,3,6,7,14,15-hexakis(azidomethyl)-9,10-dihydro-9,10-[1’,2’]benzenoanthracene). The key step of the synthesis was the cycloaddition of the azide to 2-propyn-1-yl β-D-gluco- or galactopyranosides. All products were isolated in good yields and were fully characterized.