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A Stop Scan Interferometer Used for Time-Resolved Ftir Emission-Spectroscopy

Journal article published in 1990 by P. Biggs, G. Hancock, D. E. Heard ORCID, R. P. Wayne
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

This paper describes how a low-cost teaching interferometer has been modified for use as a time-resolved instrument to study the infrared vibrational chemiluminescence of the products from atom-radical reactions and molecular photodissociations. This technique allows the entire temporal evolution of the emission spectrum to be obtained from a single interferometric scan, with spectral spectral and temporal resolutions of 2 cm-1 and 3 μs respectively. Illustrative results are given for discharge-flow studies of laser initiated atom-radical reactions, where product emission from highly vibrationally excited CO2 and HF is observed, and for emission from vibrationally excited products of the infrared multiple-photon dissociation of halocarbon molecules.