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Wiley, Angewandte Chemie International Edition, 4(52), p. 1245-1247, 2012

DOI: 10.1002/anie.201207770

Wiley, Angewandte Chemie, 4(125), p. 1283-1285, 2012

DOI: 10.1002/ange.201207770

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Ether-Directedortho-C-H Olefination with a Palladium(II)/Monoprotected Amino Acid Catalyst

Journal article published in 2012 by Gang Li ORCID, Dasheng Leow, Li Wan, Jin-Quan Yu
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Weak coordination is powerful! A PdII-catalyzed olefination of ortho-C–H bonds of arenes directed by weakly coordinating ethers is developed using mono-protected amino acid (MPAA) ligands. This finding provides a method for chemically modifying ethers, which are abundant in natural products and drug molecules.