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Wiley, Angewandte Chemie International Edition, 36(43), p. 4767-4770, 2004

DOI: 10.1002/anie.200460663

Wiley, Angewandte Chemie, 36(116), p. 4871-4874, 2004

DOI: 10.1002/ange.200460663

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Cavity Effects on the Enantioselectivity of Chiral Amido[4]resorcinarene Stereoisomers

Journal article published in 2004 by Bruno Botta ORCID, Deborah Subissati, Andrea Tafi, Giuliano Delle Monache, G. D. Monache, Antonello Filippi ORCID, Maurizio Speranza
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The dramatic effects of the size and hydrophilic/hydrophobic properties of cavities on the intrinsic reaction kinetics and dynamics is shown by the gas-phase reaction of (R)-(-)-2-butylamine and complexes of stereoisomeric amido[4]resorcinarene hosts with aromatic amino acids. The graph shows the kinetic plots of the base-induced loss of L-Phe (green), L-Tyr (red), and L-dopa (blue).