Wiley, Angewandte Chemie International Edition, 36(43), p. 4767-4770, 2004
Wiley, Angewandte Chemie, 36(116), p. 4871-4874, 2004
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The dramatic effects of the size and hydrophilic/hydrophobic properties of cavities on the intrinsic reaction kinetics and dynamics is shown by the gas-phase reaction of (R)-(-)-2-butylamine and complexes of stereoisomeric amido[4]resorcinarene hosts with aromatic amino acids. The graph shows the kinetic plots of the base-induced loss of L-Phe (green), L-Tyr (red), and L-dopa (blue).