Published in
World Scientific Publishing, Journal of Porphyrins and Phthalocyanines, 08n09(18), p. 727-734
DOI: 10.1142/s1088424614500497
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A new porphyrin dimer as an unexpected side-product
Journal article published in 2014 by
Ana M. V. M. Pereira 
,
Christophe Jeandon,
José A. S. Cavaleiro ,
Maria G. P. M. S. Neves,
Romain Ruppert
,
Christophe Jeandon,
José A. S. Cavaleiro ,
Maria G. P. M. S. Neves,
Romain Ruppert
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Abstract
The synthesis of new diporphyrinylamines is described. In particular, the possibility to use the Buchwald or Ullmann amination reactions to obtain these compounds is detailed. Attempts to obtain symmetrical diporphyrinylamines linked by a tertiary amine are exposed and the obtention as side-product of an unexpected unsymmetrical porphyrin dimer with a meso–β linkage is described.