With the development of society, environmental issues have been given more and more attention, and the improvement of public awareness, legal and environmental standards promote the rapid development of green supply chain. Combining with catastrophe progression method (CPM), enterprises who implement green supply chain are provided scientific and effective ways to manage company. Firstly, the evaluation process of CPM is given. Secondly, a set of green supply chain performance evaluation index system is designed on the basis of the connotation of green supply chain and environmental management standards, and the index system is designed by using dimensionless process. Finally, numerical examples show that the performance evaluation of green supply chain based on CPM has a higher scientific and practical application value.