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De Gruyter, Zeitschrift für Kristallographie - Crystalline Materials, 9(217), p. 464-473, 2002

DOI: 10.1524/zkri.217.9.464.22882

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Comparative topological analysis of simple anhydrous borates, carbonates and nitrates

Journal article published in 2002 by V. A. Blatov ORCID, Yu A. Zakutkin
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

Abstract Topological analysis and comparing of the crystal structures of anhydrous inorganic salts containing triangular oxo-anions (borates, carbonates and nitrates) was performed using the program package for multipurpose crystallochemical analysis TOPOS. The examples of topological similarities between these classes of substances and 2920 framework binary compounds AyXz were revealed and discussed. It is shown that in most cases the ionic arrays constructed according to one of close packings or to a b.c.c. motif can be selected in the crystal structures of anhydrous inorganic salts. The conclusions were made about the structure-forming role of atoms and atomic groups in these substances. The crystal structures of anhydrous salts are substantiated to be correctly considered as packings of metal cations and quasi-spherical oxo-anions.