Published in
Royal Society of Chemistry, RSC Advances, 82(5), p. 66534-66542
DOI: 10.1039/c5ra12201e
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Oxidation of a rollover cycloplatinated(ii) dimer by MeI: a kinetic study
Journal article published in 2015 by
Reza Babadi Aghakhanpour 
,
Mehdi Rashidi,
Fatemeh Niroomand Hosseini,
Fatemeh Raoof,
S. Masoud Nabavizadeh
,
Mehdi Rashidi,
Fatemeh Niroomand Hosseini,
Fatemeh Raoof,
S. Masoud Nabavizadeh
This paper is made freely available by the publisher.
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Abstract
The known rollover cycloplatinated(ii) complex [Pt2Me2(PPh3)2(μ-bpy-2H)], 1, in which bpy-2H acts as a bridging rollover ligand, reacts with MeI to give a new binuclear rollover cycloplatinated(iv) complex [Pt2Me4I2(PPh3)2(μ-bpy-2H)], 2.