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American Chemical Society, Organometallics, 15(33), p. 4051-4056, 2014

DOI: 10.1021/om500568q

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Secondary Phosphine Oxide–Gold(I) Complexes and Their First Application in Catalysis

Journal article published in 2014 by Felix Schroeder, Felix Schröder, Coralie Tugny, Elise Salanouve, Hervé Clavier, Laurent Giordano, Delphine Moraleda, Yves Gimbert, Virginie Mouriès-Mansuy ORCID, Jean-Philippe Goddard, Louis Fensterbank
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

A series of new secondary phosphine oxide (SPO)-gold(1) complexes have been synthesized and characterized by X-ray crystallography. Complexes exhibited dimeric structures interconnected by O-H center dot center dot center dot Cl hydrogen bonds. Their first use in homogeneous catalysis is reported and suggests a broad field of application in prototypical enyne cycloisomerization and hydroxy- and methoxycyclization reactions.