Published in

Wiley, Chemistry - A European Journal, 18(17), p. 5045-5053, 2011

DOI: 10.1002/chem.201003082

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Olefin Metathesis Featuring Ruthenium Indenylidene Complexes with a Sterically Demanding NHC Ligand

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The synthesis and characterization of two new ruthenium indenylidene complexes [RuCl(2)(SIPr)(Py)-(Ind)] 6 and [RuCl(2)(SIPr) (3-BrPy)-(Ind)] 7 featuring the sterically demanding N-heterocyclic carbene 1,3-bis(2,6-di isopropylphenyl)-4,5-dihydroimidazol-2-ylidene (SIPr) are reported. Remarkable activity was ob-served with these complexes in ring closing, enyne, and cross metathesis of olefins at low catalyst loadings. The performance of SIPr-bearing complexes 6 and 7 as well as [RuCl(2)(SIPr) (PCy(3))-(Ind)] 5 in ring opening metathesis polymerization is also disclosed. This work highlights the enormous influence of the neutral "spectator" ligands on catalyst activity and stability.