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American Chemical Society, Inorganic Chemistry, 16(43), p. 4781-4783, 2004

DOI: 10.1021/ic0351794

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Structural characterization and luminescence behavior of a silver(I) 1D polymeric chain constructed via a bridge with unusual 4,5-diazospirobifluorene and perchlorate

Journal article published in 2004 by Cheng-Han Yang, Shih-Min Tseng, Sue-Yi Lin, Ti-Yu Wu, Ming-Ren Fuh, Gene-Hsiang Lee, Ken-Tsung Wong, Ruei-Tang Chen, Yi-Ming Cheng, Pi-Tai Chou ORCID, CC; Yang CH; Tseng SM; Lin SY; Wu TY; Fuh MR; Lee GH; Wong KT; Chen RT; Cheng YM; Chou PT Wang
This paper is available in a repository.
This paper is available in a repository.

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Abstract

A new polymeric silver complex, [Ag(2)(L(2))(ClO(4))(2)] (L = 4,5-diazospirobifluorene), has been synthesized and shown to exhibit interesting luminescence properties in a single crystal. Structural analysis reveals a one-dimensional chain, which contains a [Ag(2)(L(2))](2+) dimer bridged with ClO(4)(-). The Ag...Ag distances are 2.776(1) and 4.575(1) A incorporated by two L ligands and by a ClO(4)(-) bridge, respectively.