Published in
Wiley, Angewandte Chemie International Edition, 28(52), p. 7286-7290, 2013
Wiley, Angewandte Chemie, 28(125), p. 7427-7431, 2013
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Nanosolvation-induced stabilization of a protonated peptide dimer isolated in the gas phase.
Journal article published in 2013 by
Aleksandar R. Milosavljević,
Viktor Z. Cerovski,
Francis Canon,
Laurent Nahon,
Alexandre Giuliani 
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Abstract
A dash of water: Nanosolvation of a leucine-enkephalin peptide dimer by only three water molecules has a dramatic impact on its stability to VUV photon irradiation. A drastic reduction of the fragmentation abundance of the hydrated protonated peptide dimer precursor, isolated in the gas phase, was observed. Calculations show that hydration in fact stabilizes the dimer structure.