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American Chemical Society, Inorganic Chemistry, 5(53), p. 2450-2459, 2014

DOI: 10.1021/ic402371x

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Paramagnetism of Aqueous Actinide Cations. Part I: Perchloric Acid Media

Journal article published in 2014 by Thomas F. Wall, T. F. Wall, Steve Jan ORCID, Matthieu Autillo, Kenneth L. Nash, K. L. Nash, Laetitia Guerin, Claire Le Naour, C. Le Naour, Philippe Moisy, Claude Berthon
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Magnetic susceptibilities of soluble actinide ions were revisited by NMR spectroscopy. Experimental values are compared with previously published values. An estimated order of magnitude of the paramagnetic effects can be used as probes in NMR spectroscopy. Lanthanide(III) ions are discussed in the context of 4f and 5f electrons. Measurements performed on other actinide oxidation states (IV, V, and VI) emphasize the importance of water ligand field effects on the 5f electrons.