By laser ablation we prepared thin films of the colossal magnetoresistive compound La1-xCaxMnO3 with doping levels 0.1 < x < 0.9 on MgO substrates. X-ray diffraction revealed epitaxial growth and a systematic decrease of the lattice constants with doping. The variation of the transport and magnetic properties in this doping series was investigated by SQUID magnetization and electrical transport measurements. For the nonmetallic samples resistances up to 10(13) Omega have been measured with an electrometer setup. While the transport data indicate polaronic transport for the metallic samples above the Curie temperature the low-doped ferromagnetic insulating samples show a variable range hopping like transport at low-temperature.