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Elsevier, Journal of Molecular Structure, (780-781), p. 70-79

DOI: 10.1016/j.molstruc.2005.04.051

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Stark Effect in X$_2$y$_4$ Molecules: Application to Ethylene

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

We present a development of the dipole moment and polarizability operators of X$_2$Y$_4$ molecules, using a tensorial formalism} {\bf 217}, 239-248, (2003)}$^,$}, accepted, (2005).} analogous to the one developed for tetrahedral and octahedral molecules} {\bf 228}, 620-634, (2004).}. These operators are involved in the calculation of the intensities of rovibrational transitions as well as in the calculation of the Stark effect. Expressions for the matrix elements are derived. A model for the study of the Stark effect in isolated bands of such molecules is proposed and has been used to predict the Stark spectra of the $ν_{12}$ band of ethylene. Values of the polarizability coefficients have been calculated using {\em ab initio} methods. ; {W. Raballand, M. Rotger, V. Boudon and M. Loete, {\em J. Mol. Spectrosc.{Ch. Wenger, W. Raballand, M. Rotger and V. Boudon, {\em J. Quant. Spectrosc. Radiat. Transfer{V. Boudon, J.-P. Champion, T. Gabard, M. Loete, F. Michelot, G. Pierre, M. Rotger, Ch. Wenger and M. Rey, {\em J. Mol. Spectrosc. ; Author Institution: Laboratoire de Physique de l'Uni\-versite de Bourgogne,; UMR CNRS 5027, 9, av. Alain Savary, B.P. 47870, F-21078 Dijon Cedex, France; Max-Planck-Institut fur Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mulheim an der Ruhr, Germany