Published in

Materials Research Society, Materials Research Society Symposium Proceedings, (289), 1992

DOI: 10.1557/proc-289-13

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Characterization of Monodisperse Aqueous Latex Dispersions Prepared with N-Isopropylacrylamide

Journal article published in 1992 by D. Kiminta, B. Costello, S. Lenon, P. F. Luckham ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

AbstractPoly-N-isopropylacrylamide (poly-NIPAM) is a water soluble nonionic polymer that exhibits a lower consolute solution temperature (LCST) of about 31°C. This paper describes the preparation and characterization of a monodisperse, hydrophilic polymer latex of poly-NIPAM, crosslinked by N,N'-methylenebisacrylamide. The presence of these crosslinking moieties will prevent dissolution of the particles at low temperatures; rather the particles will be swollen with solvent such that a microgel is formed. The swelling and rheological behaviour of the latex has been studied. The results show that at high temperatures the particles are ˜ 30 nm whilst at 25°C, the particles were ˜ 130 nm in diameter. This four fold increase in the particle diameter correspond to a ˜ sixty fold increase in volume. The rheological properties, both continuous and oscillatory shear, of these systems have also been studied and is strongly temperature dependant, reflecting the changes in phase volume of the NIPAM latex.