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Materials Research Society, Materials Research Society Symposium Proceedings, (965), 2006

DOI: 10.1557/proc-0965-s09-11

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Electronic Memory Effects in Zinc Oxide Nanoparticle -Polystyrene Devices with a Calcium Top Electrode

Journal article published in 2006 by Frank Verbakel, Stefan C. J. Meskers ORCID, René A. J. Janssen
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

ABSTRACTDiodes with an active layer of solution processed zinc oxide (ZnO) nanoparticles and polystyrene are studied. Poly(3,4-ethylenedioxythiophene)- polystyrenesulfonate (PEDOT:PSS) on indium doped tin oxide (ITO) is used as the bottom electrode and aluminum or calcium are used as top electrode. Pristine devices show diode behavior in their current-voltage characteristics. The conductivity of the device in reverse bias can be raised three orders of magnitude by applying a positive voltage or by illumination with UV light. In this high conductivity state we observe reversible electronic memory effects. The electronic memory effects are attributed to a reversible electrochemical process at the PEDOT:PSS/ZnO interface. Memory effects in diodes with Al and Ca metal electrode are found to be very similar, consistent with the view that the memory effects arise at the PEDOT:PSS/ZnO interface.