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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 1(64), p. m205-m205, 2007

DOI: 10.1107/s1600536807066238

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[4′-(2-Bromo-5-pyridyl)-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′]bis(triphenylphosphine-κP)copper(I) tetrafluoridoborate dichloromethane hemisolvate

Journal article published in 2007 by Matthew I. J. Polson ORCID, Garry S. Hanan, Nicholas J. Taylor
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

In the title complex, [Cu(C(20)H(13)BrN(4))(C(18)H(15)P)(2)]BF(4)·0.5CH(2)Cl(2), the copper(I) cation adopts a distorted tetra-hedral arrangement, coordinated by two triphenyl-phosphine ligands and two N atoms of the potentially tridentate terpyridine ligand. One half-mol-ecule of dichloro-methane crystallizes with the complex. The chlorine atoms are disordered over two sites with occupancies fixed at 0.30 and 0.20 respectively. The N donor atom of the central pyridine inter-acts weakly with the copper centre at a distance of 3.071 Å.