Published in
Canadian Science Publishing, Canadian Journal of Chemistry, 11(80), p. 1562-1567, 2002
DOI: 10.1139/v02-143
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Palladium and platinum complexes of L -PhePhos: Acetyl- p -(diphenylphosphino)- L -phenylalanine methyl ester a chiral ligand for transition metal complexation
Journal article published in 2002 by
Vineeth Iyengar,
Patrycja V. Galka,
Andreas Pletsch,
Heinz-Bernhard Kraatz 
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Abstract
The crystal structure of the new phenylalanine-based phosphino amino acid L-PhePhos and its reactivity to form the Pd and Pt complexes (L-PhePhos)PdCl2 and (L-PhePhos)PtCl2 is reported. A new platinum hydride was quantitatively formed in the reaction of (L-PhePhos)PtCl2 with NaBH4.Key words: phosphine, amino acid, hydride, platinum, palladium, structure.