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American Institute of Physics, Journal of Applied Physics, 2(117), p. 025304, 2015

DOI: 10.1063/1.4905790

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Electronic excitations and structure of Li2IrO3 thin films grown on ZrO$_{2}$:Y (001) substrates

This paper is available in a repository.
This paper is available in a repository.

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Abstract

Thin films are a prerequisite for application of the emergent exotic ground states in iridates that result from the interplay of strong spin-orbit coupling and electronic correlations. We report on pulsed laser deposition of Li$_{2}$IrO$_{3}$ films on ZrO$_{2}$:Y(001) single crystalline substrates. X-ray diffraction confirms preferential (001) and (10-1) out-of-plane crystalline orientations with well defined in-plane orientation. Resistivity between 35 and 300 K is dominated by a three-dimensional variable range hopping mechanism. The dielectric function is determined by means of spectroscopic ellipsometry and, complemented by Fourier transform infrared transmission spectroscopy, reveals a small optical gap of $≈$ 300 meV, a splitting of the $5d$-$t_{2g}$ manifold, and several in-gap excitations attributed to phonons and possibly magnons. ; Comment: 6 pages, 4 figures, 1 table