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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 10(64), p. o1954-o1954, 2008

DOI: 10.1107/s1600536808029085

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(S)-(−)-6-(4-Bromo­phen­yl)-2,3,5,6-tetra­hydro­thia­zolo[2,3-b]imidazolium hydrogen oxalate

Journal article published in 2008 by Thomas Minor, Maksymilian Chruszcz ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The structure of the title compound, C11H12BrN2S+·C2HO4 − (common name 6-bromo­levamisole hydrogen oxalate), is stabilized mainly by hydrogen bonds. Hydrogen oxalate anions form parallel coplanar chains via O—H⋯O hydrogen bonds, while there are N—H⋯O hydrogen-bonding inter­actions between the 6-bromo­levamisole cations and oxalate anions. Both five-membered rings from the 6-bromo­levamisole mol­ecule have a twist conformation. The mol­ecule has an extended conformation, with the 4-bromo­phenyl substituent positioned equatorially with N—C—C—C and C—C—C—C torsion angles of 39.8 (3) and 100.4 (3)°, respectively.