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Wiley, Angewandte Chemie International Edition, 21(53), p. 5310-5313, 2014

DOI: 10.1002/anie.201400655

Wiley, Angewandte Chemie, 21(126), p. 5414-5417, 2014

DOI: 10.1002/ange.201400655

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Large zero-field splittings of the ground spin state arising from antisymmetric exchange effects in heterometallic triangles.

Journal article published in 2014 by Samantha A. Magee, Stephen Sproules, Anne-Laure Barra, Grigore A. Timco, Nicholas F. Chilton ORCID, David Collison, Richard E. P. Winpenny, Eric J. L. Mcinnes
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Abstract

[Ru2Mn(O)(O(2)CtBu)(6)(py)(3)] has an S=(5)/(2) ground state with a very large zero-field splitting (ZFS) of D=2.9cm(-1), as characterized by EPR spectroscopy at 4-330GHz. This is far too large to be due to the Mn-II ion (D