This is the final version of the article. It first appeared from Wiley via http://dx.doi.org/10.1002/aelm.201500008 ; Organometallic lead perovskite-based solar cells can be converted to light-emitting diodes by engineering the current density. Diodes are fabricated with adjacent perovskite and conjugated polymer layers using orthogonal solvents. Under forward bias, these devices show simultaneous emission from both the luminescent conjugated polymer and the perovskite, providing direct information on electron and hole recombination as a function of device architecture and bias voltage. ; We gratefully acknowledge funding from the Engineering and Physical Sciences Research Council (EPSRC). A.K. acknowledges NRF-Singapore for a scholarship.