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Institute of Organic Chemistry & Biochemistry, Collection of Czechoslovak Chemical Communications, 8(75), p. 807-812

DOI: 10.1135/cccc2010053

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Macropolyhedral boron-containing cluster chemistry [S2B16H17]–. A new eighteen-vertex thiaborane anion

Journal article published in 2010 by Michael J. Carr, William Clegg ORCID, John D. Kennedy, Michael G. S. Londesborough, Colin A. Kilner
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

The novel eighteen-vertex macropolyhedral dithiaborane anion [S2B16H17]– 1 has been obtained as its [tmndH]+ salt from the reaction of [S2B17H17] 2 and tmnd in solution in the presence of [RhCl2(η5-C5Me5)]2. It has two cluster skeletal electrons more than the three previously reported eighteen-vertex dithiaborane {S2B16} species n-[S2B16H16], n-[S2B16H15]– and iso-[S2B16H16], and the anion consists structurally of an arachno {SB9} and a nido {B9} cluster unit fused with two boron atoms in common, and with an endo-to-exo sulfur bridge that also links the two subclusters together.